LOCAL MICROSTRUCTURE DEPENDENCE OF PVC INTERACTION WITH SOLVENTS - A FTIR VERIFICATION

Citation
Jm. Gomezelvira et al., LOCAL MICROSTRUCTURE DEPENDENCE OF PVC INTERACTION WITH SOLVENTS - A FTIR VERIFICATION, Macromolecular symposia, 114, 1997, pp. 151-157
Citations number
7
Categorie Soggetti
Polymer Sciences
Journal title
ISSN journal
10221360
Volume
114
Year of publication
1997
Pages
151 - 157
Database
ISI
SICI code
1022-1360(1997)114:<151:LMDOPI>2.0.ZU;2-L
Abstract
The occurrence of local configuration based PVC-solvent interactions, specifically, is demonstrated by studing, first, the changes in FTIR f requency of both the solvent carbonyl band and the PVC C-Cl stretching bands with the composition of PVC-solvent mixtures; and, secondly, th e FTIR dichroic behaviour of the same bands upon stretching PVC films containing traces of solvent. The latter turns out to be an original p ath to investigate polymer interactions.