Ne. Kotelnikova et al., STUDY OF METAL-CLUSTERS INTERCALATION INTO CELLULOSE BY WAXS, SPECTROSCOPIC, AND MICROSCOPIC METHODS, Macromolecular symposia, 114, 1997, pp. 165-171
Cellulose substrates are increasingly used as supports and fillers in
medicine, as membranes and components of organic sensors. In the prese
nt paper the WAXS as well as SEM, TEM, XRF, EDXA, ESCA, FTIR, Raman, a
nd C-13 NMR were used to study methods of metal clusters intercalation
(taking as an example silver clusters) into the cellulose matrix and
changes of cellulose structure in the resulting samples in bulk after
this intercalation. Clusters in matrix can be formed simultaneously wi
th the appearance of the metal phase proper on the cellulose surface.
Some paths for intercalation of regularly distributed highly dispersed
metal particles are shown.