M. Riva et Vg. Benza, HYDRODYNAMIC EFFECTS IN PHASE-SEPARATION - AN EXPLICIT SOLUTION APPROACH, Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics, 56(6), 1997, pp. 7001-7007
We study the influence of hydrodynamic modes on phase separation by mo
deling pure-phase domains with kinks. The velocity field, determined a
diabatically in terms of the thermodynamic source, describes a steady
state compressible flow. We consider spherical, columnar, and disklike
domains. In the former two cases, we obtain crossover from the (R) ov
er dot similar to 1/R-2 law to the R similar to t law as in the incomp
ressible case. The growth of columnar domains is dominated by hydrodyn
amics, while for spherical domains we find competition between hydrody
namics and particle diffusion: this competition determines a threshold
in size for the fluctuations, i.e., only large enough fluctuations ca
n initiate the spinodal decomposition. We finally study disklike domai
ns in a quasi-two-dimensional system and obtain, for small radii, the
growth law (R) over dot similar to 1/[R(3)ln(Lambda/R)], while for lar
ge radii (R) over dot similar to 1/[R(2)ln(Lambda/R)]. We find that st
able microdomains can be formed, whose size is fixed by the thickness
of the lamella and by the parameters of the fluid (e.g., viscosity, tr
ansport coefficient, etc.).