FACILITATED TRANSPORT OF CO2 THROUGH SUPPORTED LIQUID MEMBRANES OF VARIOUS AMINE SOLUTIONS - EFFECTS OF RATE AND EQUILIBRIUM OF REACTION BETWEEN CO2 AND AMINE

A series of experiments on the facilitated transport of CO2 through su pported liquid membranes impregnated with aqueous solutions of various amines as carriers was performed, and the effects of the reaction rat e and the chemical equilibrium of the reaction between CO2 and amine o n the permeability of CO2 were investigated. Four primary amines (mono ethanolamine (MEA), ethylenediamine (EDA), monoprotonated ethylenediam ine (EDAH(+)), 2-amino-2-methyl-1-propanol (AMP)), one secondary amine (diethanolamine (DEA)) and two tertiary amines (triethanolamine (TEA) , methyldiethanolamine (MDEA)) were used as the carrier. The feed gas was a mixture of CO2 and CH4. High CO2 permeabilities were obtained wi th the EDAN(+) membrane due to its moderate chemical equilibrium const ant Kc, which is favorable for both fast absorption of CO2 at the feed side of the membrane and fast stripping at the sweep side. Low CO2 pe rmeabilities were obtained with the tertiary amine and AMP membranes d ue to their low reactivity. The CO2 permeability through the MEA membr ane, which has too large a K-eq value at low temperature, increased wi th increasing temperature due to the decrease in K-eq and also due to the increase in the reaction rate. The experimental results obtained w ith the MEA, DEA and EDAH(+) membranes were simulated on the basis of the theory of facilitated transport.