COMPLETE VIBRATIONAL-SPECTRUM OF NICO ISOLATED IN SOLID ARGON

Authors
JOLY HA MANCERON L
Citation
Ha. Joly et L. Manceron, COMPLETE VIBRATIONAL-SPECTRUM OF NICO ISOLATED IN SOLID ARGON, Chemical physics, 226(1-2), 1998, pp. 61-70
Citations number
31
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
Chemical physics → ACNP
ISSN journal
03010104
Volume
226
Issue
1-2
Year of publication
1998
Pages
61 - 70
Database
ISI
SICI code
0301-0104(1998)226:1-2<61:CVONII>2.0.ZU;2-U
Abstract
The infrared spectrum of NiCO isolated in solid argon has been reinves tigated. Isotopic data on nu(1), nu(2), nu(3), 2 nu(1), nu(1), nu(2) a nd nu(1) + nu(3) have been measured in the near-and far-infrared regio ns. This enables a complete harmonic force-field calculation based on the assumption of a linear geometry. Comparisons with bond force const ants of Ni(CO)(4) and the latest ab initio predictions of the NiCO vib rational frequencies are also presented. (C) 1998 Elsevier Science B.V .