CATALYTIC OLIGOMERIZATION OF ETHYLENE TO LOWER ALPHA-OLEFINS BY THE CATALYST SYSTEM DPA(NA) NICL2-CENTER-DOT-6H(2)O/ZN/

Authors
LIU DB LI DG
Citation
Db. Liu et Dg. Li, CATALYTIC OLIGOMERIZATION OF ETHYLENE TO LOWER ALPHA-OLEFINS BY THE CATALYST SYSTEM DPA(NA) NICL2-CENTER-DOT-6H(2)O/ZN/, Applied catalysis. A, General, 166(2), 1998, pp. 255-258
Citations number
9
Categorie Soggetti
Chemistry Physical
Journal title
Applied catalysis. A, General → ACNP
ISSN journal
0926860X
Volume
166
Issue
2
Year of publication
1998
Pages
255 - 258
Database
ISI
SICI code
0926-860X(1998)166:2<255:COOETL>2.0.ZU;2-R
Abstract
The catalyst system DPA(Na)/NiCl2 . 6H(2)O/Zn (DPA(Na), sodium salt of diphenylphosphinoacetic acid has high activity and selectivity to for m lower alpha-olefins in the oligomerization of ethylene. The amount o f zinc highly affects the activity, and the Zn2+ which came from the o xidation of zinc is likely to enhance the selectivity to lower alpha-o lefins. The solvent used in this system offers the hydrogen of the nic kel hydride. (C) 1998 Elsevier Science B.V.