The initial stages of gas-source growth of Si(001) using disilane have
been investigated using a combination of elevated-temperature STM and
atomistic modelling. The reaction pathway from the initial adsorption
of disilane fragments up to the nucleation of short strings of epitax
ial dimers is discussed. By the use of our STM to study disilane at th
e temperatures of interest, and atomistic modelling to calculate struc
tural stability and significant activation barriers, we are able to pr
opose a complete description of the mechanisms which underlie gas-sour
ce growth. (C) 1997 Elsevier Science B.V.