H. Watanabe et al., DISCONTINUITY IN NORMAL SPECTRAL EMISSIVITY OF SOLID AND LIQUID COPPER AT THE MELTING-POINT, Metallurgical and materials transactions. A, Physical metallurgy andmaterials science, 28(12), 1997, pp. 2507-2513
Normal spectral emissivities for solid (epsilon(lambda,solid)) and liq
uid (epsilon(lambda,liquid)) copper at the melting point have been det
ermined, and the discontinuity in epsilon(lambda,liquid) and epsilon(l
ambda,solid) at the melting point has been discussed. The spectral emi
ssivity was determined by comparing the spectral radiation intensity o
f the sample to that of the fixed-point blackbody over the wavelength
range 550 to 750 nm. The samples and fixed-point blackbody were heated
in the continuous casting type cold crucible. Values of epsilon(lambd
a,liquid) and epsilon(lambda,solid) at 650 nm were 0.167 and 0.108, re
spectively. The emissivity ratio of epsilon(lambda,liquid)/epsilon(lam
bda,solid) increased from approximately 1.2 to 1.8 as the wavelength i
ncreased in the range 550 to 750 nm. The discontinuity in epsilon(lamb
da,liquid) and epsilon(lambda,solid) at the melting point has been qua
litatively explained by the optical absorption mechanism due to the in
traband transition.