OCTAISOPROPYLCHROMOCENE - THE FIRST CHROM OCENE WITH GRADUAL LOW-SPINHIGH SPIN-TRANSITION

Authors
SITZMANN H SCHAR M DORMANN E KELEMEN M
Citation
H. Sitzmann et al., OCTAISOPROPYLCHROMOCENE - THE FIRST CHROM OCENE WITH GRADUAL LOW-SPINHIGH SPIN-TRANSITION, Zeitschrift fur anorganische und allgemeine Chemie, 623(12), 1997, pp. 1850-1852
Citations number
29
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
623
Issue
12
Year of publication
1997
Pages
1850 - 1852
Database
ISI
SICI code
0044-2313(1997)623:12<1850:O-TFCO>2.0.ZU;2-E
Abstract
Octaisopropylchromocene (1) exists in a low spin state at very low tem peratures and undergoes a gradual spin transition on warming up. At 30 0 K a high spin state with four unpaired electrons has been found for solid 1 by investigation of its magnetic properties.