SYNTHESIS AND CRYSTAL-STRUCTURE OF [NA-3( H2O)(6,5)(ETOH)][PHSNS3]CENTER-DOT-3ETOH

Authors
HANSER R MERZWEILER K
Citation
R. Hanser et K. Merzweiler, SYNTHESIS AND CRYSTAL-STRUCTURE OF [NA-3( H2O)(6,5)(ETOH)][PHSNS3]CENTER-DOT-3ETOH, Zeitschrift fur anorganische und allgemeine Chemie, 624(1), 1998, pp. 10-12
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
624
Issue
1
Year of publication
1998
Pages
10 - 12
Database
ISI
SICI code
0044-2313(1998)624:1<10:SACO[H>2.0.ZU;2-Y
Abstract
Ph4Sn4S6 reacts with Na2S . 5H(2)O in aqueous acetone to form Na-3[PhS nS3]. Recrystallization of the crude product from ethanol leads to col ourless needles of [Na-3(H2O)(6,5)(EtOH)][PhSnS3]. 3EtOH 1. The crysta l structure of 1 was determined by X-ray diffraction. 1 consists of[Ph SnS3](3-) anions and sodium cations which are coordinated by water, et hanol and sulfur atoms of the [PhSnS3](3-) anions. The [PhSnS3](3-) an ion contains a tin atom which is coordinated nearly tetrahedrally by a phenyl group and three sulfur atoms. The Sn-S bonds are 237,4(2)-238, 4(2) pm.