C-60 underwent hetero Diels-Alder reaction with a carbethoxy-substitut
ed 2-aza-1,3-butadiene and trimethylsilylthio-substituted 1,3-diaza-1,
3-butadiene (which possibly reacts as trimethylsilylamino-substituted
1-thia-3-aza-1,3-butadiene) to give C-60 derivatives fused with cyclic
amino acid and thiourea, respectively. The latter was explained to ar
ise under equilibrated conditions.