B. Burghardt et al., EVALUATION OF COHERENT-STATE PATH-INTEGRALS IN STATISTICAL-MECHANICS BY MATRIX MULTIPLICATION, The Journal of chemical physics, 108(4), 1998, pp. 1562-1569
The numerical evaluation of coherent-state path-integral representatio
ns for partition functions and other quantities in equilibrium quantum
statistical mechanics is discussed. Several coherent-state path-integ
ral schemes are introduced, which differ from each other by the order
of approximation and by the operator ordering employed in the high-tem
perature approximation of the density operator. Simple one-dimensional
systems are used to test these schemes. For the harmonic oscillator,
finite-dimensional approximations to the coherent-state path integral
are calculated analytically and compared to each other and to the real
-space path integral. For anharmonic systems, integrations must be app
roximated by quadrature formulas. This leads to a matrix multiplicatio
n scheme which is tested for the double-well potential. The results ob
tained are accurate from zero temperatures way up into the high-temper
ature regime where quantum effects become negligible. This is a signif
icant advantage over traditional real-space path integral schemes whic
h break down at low temperatures. (C) 1998 American Institute of Physi
cs.