T. Wada et al., ELECTRON-BEAM DOPING BY SUPERDIFFUSION IN UNIRRADIATED REGIONS (X-LESS-THAN-300-ANGSTROM) OF SEMICONDUCTORS AT ROOM-TEMPERATURE, JPN J A P 1, 36(12B), 1997, pp. 7669-7680
Electron beam doping processes in the damageless region and at room te
mperature mere investigated before annealing. In the three-layer syste
m of layer 3/layer 2/layer I: the impurity sheet (layer 2) was sandwic
hed between two semiconductor wafers. The surface of layer 3 was irrad
iated with electron beams of 750keV and 7MeV. Interstitials of displac
ed atoms in the overlayer, which were introduced by irradiation, migra
ted to the surface of the semiconductors. These interstitials diffused
rapidly at the surface with a very large surface diffusivity of simil
ar to 10(-5) cm(2).s(-1). The diffusion process was observed using an
atomic force microscope (AFM). Impurity concentrations in the surface
layer during irradiation were found to be on the order of matrix atom
concentration. Electron irradiation produced a number of self-intersti
tials that migrated with large surface diffusivities at the surface. D
iffusion was enhanced due to the kick-out mechanism at the interface o
f the system and in the depth direction of the semiconductors.