Y. Fujiwara et al., FABRICATION OF 2-DIMENSIONAL INP PHOTONIC BAND-GAP CRYSTALS BY REACTIVE ION ETCHING WITH INDUCTIVELY-COUPLED PLASMA, JPN J A P 1, 36(12B), 1997, pp. 7763-7768
We fabricated two-dimensional (2D) InP photonic band-gap crystals by r
eactive ion etching (PIE) with a SiCl4/Ar inductively coupled plasma (
ICP) chemistry, and characterized their reflective characteristics in
the optical wavelength region by Fourier-transformed infrared reflecti
on absorption spectrometry (FTIR-RAS). The photonic band-gap crystals
consisted of a periodic array of parallel air rods of circular cross s
ection whose intersections with a perpendicular plane form a triangula
r lattice in InP substrates. Prior to the fabrication of the periodic
array of air rods, the photonic band structure for electromagnetic wav
es was calculated theoretically in the sample structure and was predic
ted to appear in the optical wavelength region. In RIE with the SiCl4/
Ar ICP chemistry, we systematically investigated the InP etch rate and
the etch selectivity of InP over SiO2 as functions of various etching
parameters, to fabricate deep air rods with a vertical profile. The e
ffect of the N2O addition to the SiCl4/Ar ICP chemistry was investigat
ed and it was revealed that the addition of a small amount of N2O resu
lts in an improvement in the vertical profile with a slight increase i
n the InP etch rate. The InP etch rate and the etch selectivity of InP
over SiO2 depended strongly on the SiCl4 flow rate. In FTIR-RAS measu
rements, characteristic features were observed in tile optical wavelen
gth region, depending on the diameter of the air rods. Behaviors of th
e features were discussed in relation to theoretically calculated dens
ities of states.