In this paper, the state profile estimation of a novel autothermal fix
ed-bed reactor (called circulation loop reactor, CLR), which can be op
erated as an autonomous periodic system, is studied. Since in autother
mal operation the reactor shows sustained large oscillations, its dyna
mics have to be modelled as a strongly nonlinear distributed parameter
system. The generally used lumping techniques (e.g. the orthogonal co
llocation method) for designing the state estimator of fixed-bed react
ors are not applicable in this case. An approach for estimating the st
ate profiles of the CLR based on a nonlinear distributed parameter obs
erver is presented. To decrease the computational effort of the observ
er in real-time applications, the reduction of the detailed model of t
he CLR is investigated. In order to achieve asymptotic stability and f
ast convergence of the observer, the observability of the CLR is analy
sed, and use of features of the sustained oscillatory system and physi
cal insight are made. A method based on exponential weighting function
s is proposed to approximate the observation error profile. The temper
ature and concentration profiles are estimated from a small number of
temperature measurements. The obtained observer was successfully teste
d with the dynamic simulator DIVA in the cases of errors in the initia
l condition and the model parameters, random noisy measurements, and u
nknown disturbances, also including the different choice of sensor loc
ations, and different observer parameters. It shows excellent dynamic
tracking of the reactor profiles, strong robustness, and easy tuning.
It forms a basis for developing appropriate control strategies of the
CLR. (C) 1997 Elsevier Science Ltd.