A. Chianese et N. Santilli, MODELING OF THE SOLID LAYER GROWTH FROM MELT CRYSTALLIZATION - THE INTEGRAL FORMULATION APPROACH, Chemical Engineering Science, 53(1), 1998, pp. 107-111
This work deals with the mathematical simulation of the solid-layer gr
owth from solid-layer melt crystallization by applying the integral fo
rmulation approach. The mathematical model here proposed has been appl
ied to the prediction of the growth of a crystal on a cylindrical cold
surface in contact with a stirred melt. Three systems, i.e, pure epsi
lon-caprolactam, mixtures of epsilon-caprolactam and water and pure na
phtalene, have been examined. The data for the first two systems have
been obtained by means of an easy experimental procedure. In all cases
the proposed model provided a very good prediction of the experimenta
l data. Finally, a comparison was made between the prediction of the c
rystal-layer growth by means of the developed model and a simplified q
uasi-steady state one. (C) 1997 Elsevier Science Ltd.