COMMENT ON NUCLEAR-SPIN RELAXATION AND NONERGODIC QUASI-EQUILIBRIA

Authors
SKRYNNIKOV NR BRUSCHWEILER R
Citation
Nr. Skrynnikov et R. Bruschweiler, COMMENT ON NUCLEAR-SPIN RELAXATION AND NONERGODIC QUASI-EQUILIBRIA, Chemical physics letters, 281(1-3), 1997, pp. 239-242
Citations number
20
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
Chemical physics letters → ACNP
ISSN journal
00092614
Volume
281
Issue
1-3
Year of publication
1997
Pages
239 - 242
Database
ISI
SICI code
0009-2614(1997)281:1-3<239:CONRAN>2.0.ZU;2-Y
Abstract
Spin relaxation is described for a system of three accidentally degene rate nuclear spins that can be individually monitored, e.g., via heter onuclear scalar coupling partners. The exact treatment based on Bloch- Wangsness-Redfield theory is shown to be consistent with the stochasti c Liouville equation correcting and extending earlier findings (Brusch weiler, Chem. Phys. Lett. 270 (1997) 217). The transition to the Solom on regime is discussed when degeneracy is removed. (C) 1997 Elsevier S cience B.V.