EFFECT OF LIBR ADDITION TO 1-METHYL-2-PYRROLIDINONE IN THE SIZE-EXCLUSION CHROMATOGRAPHY OF COAL-DERIVED MATERIALS

Two propositions relating to the interpretation of size-exclusion chro matograms (SEC) of coal-derived materials in 1-methyl-2-pyrrolidinone (NMP) have been examined. These were iii that signal peaks showing up at exclusion (short retention time) limits of SEC columns are due to s ample polarity alone and (ii) that shifts in SEC chromatograms to long er retention times, observed upon addition of LiBr to the eluent (NMP) , are due to dissipation of ionic binding forces, causing disaggregati on of polar clusters that would otherwise have appeared at retention t imes appropriate to larger molecular masses. In our experiments, effec ts due to polarity and molecular mass have been isolated by using two nonpolar samples (a naphthalene mesophase pitch and a mixture of fulle renes). In the presence of LiBr, precipitation of solute out of soluti on and shifts of chromatograms to longer retention times, unrelated to sample polarity, have been observed. A partial breakdown of the size exclusion mechanism was identified by the observed extension of chroma tograms beyond the permeation limit of the column, similar to those ob served when using eluents of insufficient solvent strength (e.g., THF, chloroform). Dosing LiBr into NMP sharply reduces the solvent power o f NMP for coal-derived solutes. In the absence of LiBr, SEC chromatogr ams of the fullerene mixture, the naphthalene mesophase pitch, and its fractions separated by planar chromatography clearly showed significa nt signal under the ''excluded'' peak, entirely due to nonpolar materi al. The damage caused to the SEC column arising from precipitation of sample, in the presence of LiBr, was not permanent as had originally b een feared. The balance of the evidence suggests that polarity of some molecules may cause shifts in their elution times to shorter values ( larger apparent molecular masses) and that these may overlap with sign al from large molecular mass material.