On-chip interconnects with copper metallization and polymer interlevel
dielectrics (ILDs) have the lowest R-C delay, lowest parasitic coupli
ng and highest electromigration resistance of currently proposed room
temperature material sets. Patterning of such interconnect structures
requires either damascene patterning (chemical-mechanical planarizatio
n (CMP) of copper deposited into trenches and via reactive ion etching
(RIE) into the polymer) or elevated temperature RIE patterning of the
copper. In this paper we present the dual damascene patterning of cop
per on low dielectric constant polymers like divinylsiloxane bisbenzoc
yclobutene (DVS bis BCB) and parylene-n. In particular, we present and
discuss various RIE polymer etch masks and CMP polish stops that have
been utilized in this work (such as PECVD silicon nitride, PECVD sili
con dioxide and tantalum) and the results with different pads and slur
ries. Emphasis is placed on achieving a planar copper CMP with a minim
um amount of polish stop and polymer ILD erosion, as well as attaining
low contact resistance. Difficulties in achieving these desirable fea
tures with relatively soft low dielectric constant polymers are presen
ted, with contact resistivity in the mid 10(-9) Ohm-cm(2) having been
achieved to date. (C) 1997 Elsevier Science S.A.