SYNTHESIS AND SOME PROPERTIES OF CHARGE-TRANSFER COMPLEXES OF C-60 WITH ASYMMETRIC DONORS OF TETRATHIAFULVALENE FAMILY

Authors
KONAREV DV SHULGA YM ROSHCHUPKINA OS LYUBOVSKAYA RN
Citation
Dv. Konarev et al., SYNTHESIS AND SOME PROPERTIES OF CHARGE-TRANSFER COMPLEXES OF C-60 WITH ASYMMETRIC DONORS OF TETRATHIAFULVALENE FAMILY, Journal of physics and chemistry of solids, 58(11), 1997, pp. 1869-1872
Citations number
14
Journal title
Journal of physics and chemistry of solids → ACNP
ISSN journal
00223697
Volume
58
Issue
11
Year of publication
1997
Pages
1869 - 1872
Database
ISI
SICI code
0022-3697(1997)58:11<1869:SASPOC>2.0.ZU;2-W
Abstract
New charge transfer complexes: (TMDTDM-TTF)(2)C-60(CS2)(3), TMDTDM-TTF . C-60. C6H6, (EDT-TTF)(2)C60CS2 were synthesized by the reaction of C-60 with asymmetric donors in CS2 and benzene. XPS- and IR-spectrosco py show a weak charge transfer in these compounds. The influence of th e solvents during the formation of the complexes was disscussed. The ( TMDTDM-TTF)(2)C-60(CS2)(3) crystal structure reveals that it has a lay ered structure with alternating sheets of C-60 and donor dimers. (C) 1 997 Elsevier Science Ltd.