TRITYLTITANIUM COMPLEXES - X-RAY STRUCTURAL CHARACTERIZATION OF [TI(CO)(4)(ETA(5)-C(4-C6H4R)(3))](-) (R = H, OCH3)(1)

Authors
FISCHER PJ AHRENDT KA YOUNG VG ELLIS JE
Citation
Pj. Fischer et al., TRITYLTITANIUM COMPLEXES - X-RAY STRUCTURAL CHARACTERIZATION OF [TI(CO)(4)(ETA(5)-C(4-C6H4R)(3))](-) (R = H, OCH3)(1), Organometallics, 17(1), 1998, pp. 13-15
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
17
Issue
1
Year of publication
1998
Pages
13 - 15
Database
ISI
SICI code
0276-7333(1998)17:1<13:TC-XSC>2.0.ZU;2-Y
Abstract
Reactions of [Ti(CO)(6)](2-) and chlorotriphenyl-methane or chlorotris (4-methoxyphenyl)methane provide the first examples of trityltitanium complexes. These have been shown by IR, NMR, and single-crystal X-ray structural characterizations to have the molecular formula [Ti(CO)(4){ eta(5)-C(4-C6H4R)(3)}](-) (R = H, OCH3).