SYNTHESIS AND CHARACTERIZATION OF THE HOMOBIMETALLIC [BIS(2-HYDROXY-1-NAPHTHALDEHYDE) OXALOYLDIHYDRAZONATO]-BISDIOXOMOLYBDENUM(VI) TETRAHYDRATE COMPLEX AND ITS REACTIVITY TOWARDS PROTON AND ELECTRON-DONOR REAGENTS

Authors
LAL RA ADHIKARI S PAL A SIVA AN KUMAR A
Citation
Ra. Lal et al., SYNTHESIS AND CHARACTERIZATION OF THE HOMOBIMETALLIC [BIS(2-HYDROXY-1-NAPHTHALDEHYDE) OXALOYLDIHYDRAZONATO]-BISDIOXOMOLYBDENUM(VI) TETRAHYDRATE COMPLEX AND ITS REACTIVITY TOWARDS PROTON AND ELECTRON-DONOR REAGENTS, Journal of chemical research. Synopses, (4), 1997, pp. 122
Citations number
41
Categorie Soggetti
Chemistry
Journal title
Journal of chemical research. Synopses → ACNP
ISSN journal
03082342
Issue
4
Year of publication
1997
Database
ISI
SICI code
0308-2342(1997):4<122:SACOTH>2.0.ZU;2-C
Abstract
The homobimetallic molybdenum(vi) complexes [(MoO2)(2)(napoxlh)]. 4H(2 )O 1, [{(mu(2)-O)MoO2}MoO2(napoxlhH(2))]. 2L . 4H(2)O, [L=pyridine (py ) 2, 3-pic 3] and the molybdenum(v) complexes [MoO2(napoxlh)(sylsh)(2) ]. 5H(2)O 4 and [Mo-2(napoxlh)(inh)(2)(H2O)(2)]. 3H(2)O 5, (3-pic = 3- picoline, sylshH(3) = salicyloylhydrazine and inhH(3) = isonicotinoylh ydrazine) are synthesized from bis(2-hydroxy-1-naphthaldehyde) oxaloyl dihydrazone (napoxlhH(4)) and then characterized.