D. Lesueur et al., EVIDENCE OF A HARD SOFT RELAXATION IN A P OLYMER-MODIFIED BITUMEN/, Comptes rendus de l'Academie des sciences. Serie II. Mecanique, physique, chimie, astronomie, 325(11), 1997, pp. 615-620
A micromechanical relaxation is observed in a heterogeneous Polymer Mo
dified Bitumen (PMB). This relaxation, theoritically studied by Frohli
ch and Sack, arises when a microscopic elastic deformation develops in
dispersed phase particles. Thus, two reinforcement domains are highli
ghted when the material is sheared under a low-strain dynamic mechanic
al deformation: at low frequency, the polymer-rich dispersed particles
are harder than the matrix and behave as hard spheres (undeformable i
nclusions). At high frequencies, they are soft (deformable), causing a
subsequent decrease in the modulus of the PMB. The hard/soft relaxati
on results in a minimum of phase angle versus frequency.