PREPARATION AND REACTIVITY OF CYCLODEC-2-YN-1-ONE

Authors
ROBERTSON J BURROWS JN
Citation
J. Robertson et Jn. Burrows, PREPARATION AND REACTIVITY OF CYCLODEC-2-YN-1-ONE, Synthesis, (1), 1998, pp. 63
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis → ACNP
ISSN journal
00397881
Issue
1
Year of publication
1998
Database
ISI
SICI code
0039-7881(1998):1<63:PAROC>2.0.ZU;2-9
Abstract
The preparation, by silicon-accelerated Friedel-Crafts alkylation, and Diels-Alder reaction of cyclodec-2-yn-1-one is reported. The ynone is shown to be unstable with respect to chromatography on silica gel, is omerising to bicyclo[4.4.0]dec-1(6)-en-2-one.