ONE-POT SYNTHESIS OF TERTIARY ALPHA, OMEGA-DIAMINES VIA CARBONYLATIVEBIS[HYDROAMINOMETHYLATION] OF ALPHA,OMEGA-DIOLEFINS USING (MU-CHLORO)BIS(ETA(4)-1,5-CYCLOOCTADIENE)DIRHODIUM AS A CATALYST PRECURSOR

Authors
KRANEMANN CL EILBRACHT P
Citation
Cl. Kranemann et P. Eilbracht, ONE-POT SYNTHESIS OF TERTIARY ALPHA, OMEGA-DIAMINES VIA CARBONYLATIVEBIS[HYDROAMINOMETHYLATION] OF ALPHA,OMEGA-DIOLEFINS USING (MU-CHLORO)BIS(ETA(4)-1,5-CYCLOOCTADIENE)DIRHODIUM AS A CATALYST PRECURSOR, Synthesis, (1), 1998, pp. 71
Citations number
30
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis → ACNP
ISSN journal
00397881
Issue
1
Year of publication
1998
Database
ISI
SICI code
0039-7881(1998):1<71:OSOTAO>2.0.ZU;2-0
Abstract
Tertiary alpha,omega-diamines are selectively prepared in high yields by the reaction of alpha,omega-diolefins with secondary amines, carbon monoxide and hydrogen in the presence of [Rh(cod)Cl](2) as a catalyst precursor. This one-pot synthesis proceeds via a hydroformylation-ami ne condensation-reduction sequence and leads to a mixture of n,n-, n,i so-, and iso,iso-products.