QUANTITATIVE MONITORING OF VOLATILE ORGANIC-COMPOUNDS IN WATER USING AN EVANESCENT FIBER OPTIC CHEMICAL SENSOR

This work evaluates the usefulness of two linear chemometric algorithm s, principle component regression and partial least-squares analysis, for modeling the responses of an evanescent fiber optic chemical senso r to aqueous mixtures of organic analytes with individual concentratio ns ranging from 50 to 200 ppm. Two data sets were examined. One contai ned trichloroethylene, 1,1,2 trichloroethane, toluene, and chloroform. The second set contained these four analytes as well as tetrachloroet hene. Both chemometric algorithms performed comparably on a given data set with cross-validated root mean squared errors of prediction (RMSE P) for trichloroethylene, 1,1,2 trichloroethane, toluene, and chlorofo rm of approximately 6, 9, 6, and 16 ppm from the first set and 7, 11, 13, and 31 ppm from the second set with tetrachloroethene RMSEP of 31 ppm. The decrease in the quantitative performance of the algorithm for modeling toluene and chloroform upon addition of tetrachloroethene to the sample solutions is due to increased intensity of cladding absorp tion features in the spectral response matrix. These features overlap with the analyte absorption features of toluene and chloroform and rev eal one of the limitations with this type of sensing format.