INTRAMOLECULAR COORDINATION OF AN ALKENE TO A MIXED DICYCLOPENTADIENYL BENZYL ZIRCONIUM CATION STUDIED BY NMR-SPECTROSCOPY

Authors
GALAKHOV MV HEINZ G ROYO P
Citation
Mv. Galakhov et al., INTRAMOLECULAR COORDINATION OF AN ALKENE TO A MIXED DICYCLOPENTADIENYL BENZYL ZIRCONIUM CATION STUDIED BY NMR-SPECTROSCOPY, Chemical communications, (1), 1998, pp. 17-18
Citations number
28
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
1
Year of publication
1998
Pages
17 - 18
Database
ISI
SICI code
1359-7345(1998):1<17:ICOAAT>2.0.ZU;2-T
Abstract
Benzylation of [Zr(eta(5)-C5H5){eta(5)-C5H4SiMe2(CH2CH=CH2)}Cl-2] 1 yi elds 5)-C5H5){eta(5)-C5H4SiMe2(CH2CH=CH2)}(CH2C6H5)(2)] 2, which react s with either B(C6F5)(3) or [Ph3C][B(C6F5)(4)] to generate the same ca tion, 3+, which has been fully characterised by H-1, C-13 NMR and H-1 DNMR spectroscopy.