STEREOSELECTIVE FORMATION OF (Z)-GAMMA-SUBSTITUTED ALLYLSILANES BY THE TITANOCENE(II)-PROMOTED REACTION OF THIOACETALS WITH TRIALKYL(ALLYL)SILANES

Authors
FUJIWARA T TAKAMORI M TAKEDA T
Citation
T. Fujiwara et al., STEREOSELECTIVE FORMATION OF (Z)-GAMMA-SUBSTITUTED ALLYLSILANES BY THE TITANOCENE(II)-PROMOTED REACTION OF THIOACETALS WITH TRIALKYL(ALLYL)SILANES, Chemical communications, (1), 1998, pp. 51-52
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
1
Year of publication
1998
Pages
51 - 52
Database
ISI
SICI code
1359-7345(1998):1<51:SFO(AB>2.0.ZU;2-H
Abstract
The reaction of organotitanium species prepared by the desulfurizative titanation of thioacetals with (C5H5)(2)Ti[P(OEt)(3)](2) in the prese nce of trialkyl(allyl)silanes gives gamma-substituted allylsilanes wit h Z stereoselectivity.