ACTIVE CATALYSTS PREPARED USING A VANADIUM-CONTAINING OLIGOSILSESQUIOXANE FOR SELECTIVE PHOTO-ASSISTED OXIDATION OF METHANE INTO METHANAL

Authors
WADA K NAKASHITA M YAMAMOTO A MITSUDO T
Citation
K. Wada et al., ACTIVE CATALYSTS PREPARED USING A VANADIUM-CONTAINING OLIGOSILSESQUIOXANE FOR SELECTIVE PHOTO-ASSISTED OXIDATION OF METHANE INTO METHANAL, Chemical communications, (1), 1998, pp. 133-134
Citations number
11
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
1
Year of publication
1998
Pages
133 - 134
Database
ISI
SICI code
1359-7345(1998):1<133:ACPUAV>2.0.ZU;2-D
Abstract
Catalysts of characteristic pore structure derived from silica-support ed vanadium-containing silsesquioxane show excellent activity towards the selective photo-assisted catalytic oxidation of methane into metha nal (at 493 K, 139 mu mol h(-1) TON ca. 9h(-1), selectivity 81%), indi cating its potent abilities as an excellent precursor for porous oxide catalysts.