Radiative transfer calculations that utilize the scalar approximation
of light produce intensity errors as large as 10% in the case of pure
Rayleigh scattering. This modeling error, which arises primarily from
second order scattering, is greatly reduced for flux and albedo result
s because of error cancellation brought about by integration over scat
tering angle. However, polarized light scattered from an underlying oc
ean surface, or from atmospheric aerosols, interacts with the pattern
of Rayleigh scattered polarization to distort the error cancellation a
nd thus incur larger flux and albedo errors. While addition of scatter
ed radiation from clouds, aerosols or ground surface into the Rayleigh
atmosphere tends to reduce the magnitude of scalar approximation inte
nsity errors, the scalar errors in fluxes and albedos are not proporti
onately reduced, but are actually increased.