D. Bertin et al., LIVING RADICAL POLYMERIZATION OF MMA IN T HE PRESENCE OF PIPERIDINO-DITHIOCARBAMATE DERIVATIVES AS PHOTOINIFERTERS, European Polymer Journal, 34(1), 1998, pp. 85-90
Radical polymerizations of methyl methacrylate were carried out in the
presence of photoiniferters (RDC) containing a piperidino-dithiocarba
mate group. The effects of the structure of the RDC on the photopolyme
rization in the presence or absence of a transfer agent such as tetrae
thylthiuram disulfide (TD) were investigated. The influence of the pre
sence of a transfer agent (TD) on the living character and the control
of the polymerization were also discussed. (C) 1997 Elsevier Science
Ltd.