Di. Cendon et al., THE ORIGIN OF BARREN BODIES IN THE SUBIZA POTASH DEPOSIT, NAVARRA, SPAIN - IMPLICATIONS FOR SYLVITE FORMATION, Journal of sedimentary research, 68(1), 1998, pp. 43-52
''Barren bodies'' are meter-size lens-like features in sylvite beds wh
ere sylvite is absent or depleted, They are commonly found when mining
potash deposits, Most barren bodies are believed to be formed by sele
ctive dissolution of sylvite, due to the circulation of diagenetic or
later fluids, Contrary to this commonly favored postdepositional inter
pretation, barren bodies of the Subiza mine, Navarra, Spain are though
t to be the result of synsedimentary processes, This potash deposit co
ntains a 100 m thick Upper Eocene succession of alternating claystone
and evaporites (sulfate, halite, and sylvite), The evaporites accumula
ted in an elongated basin forming one of the depocenters of the 250 km
long South Pyrenean foreland basin, Along the margin of the basin, sl
ope instability, promoted probably by tectonism, created mass wasting,
forming mounds 0.5-2 m high and tens of meters in extension, As evapo
ration progressed, two stratified brines formed, Halite precipitated a
t the air-brine interface and sank to the bottom of the basin with ter
rigenous clays, Sylvite, however, precipitated from the lower brine, T
he mounds extended into the upper brine, thus sylvite did not precipit
ate over these upper zones, With progressive deposition the lower brin
e covered the mounds, the sylvite beds overlapping the mounds, The min
eralogical and petrographical features of the barren bodies and their
surroundings are continuous, Analyses of primary fluid inclusions from
the halites of the barren bodies show a Mg-K-Cl rich composition, Thi
s corresponds to a primary brine and is unlike the Na-CI rich brines e
xpected from replacement processes, The thickness of the sylvite-formi
ng brine (< 1 m) inferred from the mounds is inconsistent with the thi
ckness required to form centimeter-thick beds of sylvite in a closed b
asin, Alternatively, the existence of a more restricted subbasin, open
to a halite-forming basin similar to that observed in saline ponds, i
s proposed, Numerical simulations of the evaporation processes under t
hese conditions give results that match the mineral associations obser
ved and the solute content of the fluid inclusions.