EFFECT OF 3,5-DICHLOROPHENOL ON THE EXTRACTION OF TECHNETIUM COMPLEXES WITH TETRAPHENYLARSONIUM CHLORIDE

Citation
T. Omori et al., EFFECT OF 3,5-DICHLOROPHENOL ON THE EXTRACTION OF TECHNETIUM COMPLEXES WITH TETRAPHENYLARSONIUM CHLORIDE, Journal of radioanalytical and nuclear chemistry, 224(1-2), 1997, pp. 39-43
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Analytical","Nuclear Sciences & Tecnology
ISSN journal
02365731
Volume
224
Issue
1-2
Year of publication
1997
Pages
39 - 43
Database
ISI
SICI code
0236-5731(1997)224:1-2<39:EO3OTE>2.0.ZU;2-#
Abstract
The distribution behavior of pertechnetate and tetrachloronitridotechn etate(VI) with tetraphenylarsonium chloride (TPAC) was highly affected in the presence of 3,5-dichlorophenol(3,5-DCP). In both cases the dis tribution ratios of the technetium complexes decrease with an increase in the concentration of 3,5-DCP and no synergistic effect was observe d. These features could quantitatively be explained by the formation o f an associated complex of TPAC and 3,5-DCP in chloroform solution.