T. Omori et al., EFFECT OF 3,5-DICHLOROPHENOL ON THE EXTRACTION OF TECHNETIUM COMPLEXES WITH TETRAPHENYLARSONIUM CHLORIDE, Journal of radioanalytical and nuclear chemistry, 224(1-2), 1997, pp. 39-43
The distribution behavior of pertechnetate and tetrachloronitridotechn
etate(VI) with tetraphenylarsonium chloride (TPAC) was highly affected
in the presence of 3,5-dichlorophenol(3,5-DCP). In both cases the dis
tribution ratios of the technetium complexes decrease with an increase
in the concentration of 3,5-DCP and no synergistic effect was observe
d. These features could quantitatively be explained by the formation o
f an associated complex of TPAC and 3,5-DCP in chloroform solution.