The technique of pulsed field ionization-zero kinetic energy photoelec
tron spectroscopy, typically applied to the investigation of ionic sta
tes of atoms and molecules resulting from single electron excitation,
has been used to probe the correlation satellite states of xenon betwe
en 23.6-24.7 eV. The resulting spectra show the formation of clearly r
esolved satellite states with intensities of a similar magnitude to th
at of the 5s5p(62)S(1/2) ionic state. This technique can be extended t
o other atomic and molecular species to obtain the positions and cross
sections for the formation of such states.