ELECTROCHEMICAL-BEHAVIOR OF A LITHIUM TITANIUM SPINEL COMPOUND SYNTHESIZED VIA A SOL-GEL PROCESS

Authors
BACH S PEREIRARAMOS JP BAFFIER N
Citation
S. Bach et al., ELECTROCHEMICAL-BEHAVIOR OF A LITHIUM TITANIUM SPINEL COMPOUND SYNTHESIZED VIA A SOL-GEL PROCESS, Journal of materials chemistry, 8(1), 1998, pp. 251-253
Citations number
14
Categorie Soggetti
Chemistry Physical","Material Science
Journal title
Journal of materials chemistry → ACNP
ISSN journal
09599428
Volume
8
Issue
1
Year of publication
1998
Pages
251 - 253
Database
ISI
SICI code
0959-9428(1998)8:1<251:EOALTS>2.0.ZU;2-B
Abstract
The synthesis and the structural features of a mixed lithium titanium spinel Li4/3Ti5/3O4 obtained via a sol-gel process in nonaqueous media are reported. Electrochemical lithium insertion occurs in one reducti on process located at 1.550 V, and corresponds to the insertion of 1 L i per Li4/3Ti5/3O4 (150 A h kg(-1))in octahedral sites. During cycling experiments performed at discharge-charge rates of C/20, a stabilizat ion of the specific capacity around 105 A h kg (-1) (0.7 F mol(-1)) oc curs after the 20th cycle.