TEMPERATURE-DEPENDENCE OF THE DENSITY OF AN IONIC MICELLAR SYSTEM NEAR THE CRITICAL-POINT

Citation
A. Compostizo et al., TEMPERATURE-DEPENDENCE OF THE DENSITY OF AN IONIC MICELLAR SYSTEM NEAR THE CRITICAL-POINT, Chemical physics, 212(2-3), 1996, pp. 301-310
Citations number
21
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
ISSN journal
03010104
Volume
212
Issue
2-3
Year of publication
1996
Pages
301 - 310
Database
ISI
SICI code
0301-0104(1996)212:2-3<301:TOTDOA>2.0.ZU;2-Q
Abstract
The density of the system dodecylammonium chloride + water + KCI has b een studied as a function of temperature and surfactant composition fo r two different concentrations of KCI. The data of the critical sample s can be described using scaling laws and the 3D Ising value for the c ritical exponent alpha. The range of validity of simple scaling for th e density is found to be larger than for the order parameter. When com bined with previously reported data, the present results confirm the v alidity of the two-scale factor universality hypothesis in this ionic micellar system. The results obtained for off-critical compositions ha ve been found to be compatible with predictions of the so-called linea r model.