REACTION-MECHANISM AND STRUCTURE OF PRODUCTS IN PHOTOCHEMICAL-TRANSFORMATIONS OF COPPER(II) HEPTAFLUOROBUTYRATE IN METHANOL

Authors
GLEBOV EM PLYUSNIN VF GRIVIN VP DANILOVICH VS KRUPODER SA LISKOVSKAYA TI TRUNOVA VA
Citation
Em. Glebov et al., REACTION-MECHANISM AND STRUCTURE OF PRODUCTS IN PHOTOCHEMICAL-TRANSFORMATIONS OF COPPER(II) HEPTAFLUOROBUTYRATE IN METHANOL, Journal of structural chemistry, 38(4), 1997, pp. 550-555
Citations number
19
Journal title
Journal of structural chemistry → ACNP
ISSN journal
00224766
Volume
38
Issue
4
Year of publication
1997
Pages
550 - 555
Database
ISI
SICI code
0022-4766(1997)38:4<550:RASOPI>2.0.ZU;2-C
Abstract
The mechanism of photochemical transformations of copper(II) heptafluo robutyrate in methanol is studied. The structure of products and inter mediate compounds is investigated. Photolysis occurs as a two-step pro cess. The first step involves changes in the coordination sphere of th e Cu(II) ion. The second step is photoreduction of Cu(II) forming meta llic copper and Cu(II) fluoride as a complex with methanol. In the pre sence of oxygen, the first step is reversible. A scheme of these proce sses is suggested.