ORTHO-BIS(AMINO)ARYLNICKEL(II) HALIDE-COMPLEXES CONTAINING PERFLUOROALKYL CHAINS AS MODEL CATALYST PRECURSORS FOR USE IN FLUOROUS BIPHASE SYSTEMS

A novel synthetic procedure is presented to modify 1,3-bis[(dimethylam ino)methyl]benzene to accommodate perfluoro alkyl chains. These ligand s are then converted into nickel-and platinum-chloride organometallic derivatives, which can serve as model compounds for use in homogeneous catalysis. A nickel complex is shown to be an active catalyst for the 1 : 1 addition of CCl4 to methylmethacrylate (Kharasch addition react ion) in dichloromethane but lacks sufficient solubility for use under fluorous biphase conditions. The structure in the solid state of this fluorous Ni species, which is a rare example of a structurally charact erised perfluoro organometallic compound, was elucidated by single cry stal X-ray diffraction. (C) 1998 Elsevier Science Ltd. All rights rese rved.