STEREOSELECTIVE AND REGIOSELECTIVE BROMINATION OF 1,5-CYCLOOCTADIENE DERIVATIVES AND THEIR SUBSTITUTION-REACTIONS WITH ORGANOCOPPER REAGENTS

Authors
BABA Y NOUTARY C ICHIKAWA S KUSUMOTO T WATANABE H ADACHI M HOTTA H NAKAJIMA Y ARAI K HIYAMA T
Citation
Y. Baba et al., STEREOSELECTIVE AND REGIOSELECTIVE BROMINATION OF 1,5-CYCLOOCTADIENE DERIVATIVES AND THEIR SUBSTITUTION-REACTIONS WITH ORGANOCOPPER REAGENTS, Synlett, (12), 1997, pp. 1393-1394
Citations number
12
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
12
Year of publication
1997
Pages
1393 - 1394
Database
ISI
SICI code
0936-5214(1997):12<1393:SARBO1>2.0.ZU;2-4
Abstract
Bromination of tetramethyl cyclooctadiene-1,2,5,6-tetracarboxylate wit h N-bromosuccinimide took place with high selectivity to give the corr esponding 3,7-cis-dibromide, which allowed us to introduce two (the sa me or different) alkyl substituents at C(3) and C(7) with one-step or stepwise use of organocopper reagents.