A simple, inexpensive method involving chemical deposition of silver m
etal onto a polymer layer by noncatalytic chemical reduction from silv
er nitrate solution is used in the fabrication of polymeric light-emit
ting diodes (LEDs). The method yielded silver films with good polymer/
metal interfaces and the resulting LEDs emitted light uniformly over t
he entire device area, but the emission efficiencies were lower by an
order of magnitude compared to LEDs with vacuum-deposited metal electr
odes, The chemical deposition of the metal film was carried out on a l
ab bench in open air without any special precautions. In addition to i
ts cost advantage over vacuum deposition methods, the chemical process
may also allow fabrication of polymer LEDs on nonflat and/or large ar
ea substrates.