SELECTIVE ION-EXCHANGE INTERCALATION OF ISOMERIC DICARBOXYLATE ANIONSINTO THE LAYERED DOUBLE HYDROXIDE [LIAL2(OH)(6)]CL-CENTER-DOT-H2O

Authors
FOGG AM DUNN JS SHYU SG CARY DR OHARE D
Citation
Am. Fogg et al., SELECTIVE ION-EXCHANGE INTERCALATION OF ISOMERIC DICARBOXYLATE ANIONSINTO THE LAYERED DOUBLE HYDROXIDE [LIAL2(OH)(6)]CL-CENTER-DOT-H2O, Chemistry of materials, 10(1), 1998, pp. 351-355
Citations number
24
Categorie Soggetti
Chemistry Physical","Material Science
Journal title
Chemistry of materials → ACNP
ISSN journal
08974756
Volume
10
Issue
1
Year of publication
1998
Pages
351 - 355
Database
ISI
SICI code
0897-4756(1998)10:1<351:SIIOID>2.0.ZU;2-S
Abstract
The dicarboxylate anions 1,4-benzenedicarboxylate and fumarate can be selectively intercalated into the layered double hydroxide [LiAl2(OH)( 6)]Cl . H2O from equimolar molar mixtures of the 1,2-, 1,3-, and 1,4-b enzenedicarboxylate and fumarate and maleate isomers, respectively. Ti me-resolved in situ energy-dispersive X-ray diffraction studies have s hown that these are the thermodynamic products following the conversio n of an initial phase in which all the anions are simultaneously inter calated.