FORMATION OF SAMARIUM OXIDES FROM ITS CHLORIDE IN MOLTEN EUTECTIC MIXTURE OF SODIUM AND CESIUM CHLORIDES - A POTENTIOMETRIC STUDY

Authors
SMOLENSKII VV BOVE AL DELMUKHAMETOV RD BORODINA NP GAVRILOV AG
Citation
Vv. Smolenskii et al., FORMATION OF SAMARIUM OXIDES FROM ITS CHLORIDE IN MOLTEN EUTECTIC MIXTURE OF SODIUM AND CESIUM CHLORIDES - A POTENTIOMETRIC STUDY, Russian journal of electrochemistry, 33(12), 1997, pp. 1311-1315
Citations number
12
Journal title
Russian journal of electrochemistry → ACNP
ISSN journal
10231935
Volume
33
Issue
12
Year of publication
1997
Pages
1311 - 1315
Database
ISI
SICI code
1023-1935(1997)33:12<1311:FOSOFI>2.0.ZU;2-F
Abstract
The interaction between cations of trivalent samarium and oxide ions i n the NaCl-2CsCl melt is studied at 973 K by the potentiometric method , using an electrochemical cell containing two platinum-oxygen electro des with a solid electrolyte membrane. The interaction mechanism and c omposition of the reaction products are considered as a function of th e oxyacidity of the environment. Some thermodynamic characteristics of the process are calculated.