GENERATION OF CHIRAL BIS(CYCLOPENTADIENYL)NEODYMIUM SCHIFF-BASE COMPLEX BEARING INTERNAL C-C BOND FORMATION AND HYDROGEN-TRANSFER

Authors
LIU QC DING MX LIN YH XING Y
Citation
Qc. Liu et al., GENERATION OF CHIRAL BIS(CYCLOPENTADIENYL)NEODYMIUM SCHIFF-BASE COMPLEX BEARING INTERNAL C-C BOND FORMATION AND HYDROGEN-TRANSFER, Journal of organometallic chemistry, 548(2), 1997, pp. 139-142
Citations number
16
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
548
Issue
2
Year of publication
1997
Pages
139 - 142
Database
ISI
SICI code
0022-328X(1997)548:2<139:GOCBSC>2.0.ZU;2-O
Abstract
NdCl3 reacts with excess CpNa (Cp=Cyclopentadienyl) in THF, followed b y sequent treatment with (S)-(+)-N-(1-phenylethyl)salicylideneamine le d to the formation of title compound, [GRAPHICS] The X-ray structure d etermination shows that it is a dimer with internal C-C bond formation and hydrogen transfer between one of Cp ring and the C=N bond of Schi ff base ligand. (C) 1997 Elsevier Science S.A.