ON THE FORMATION OF (CH3)(4)RE2O4 FROM METHYL TRIOXORHENIUM COMPLEX CH3REO3 UNDER NON-ALKYLATING CONDITIONS

Authors
RUDLER H GREGORIO JR DENISE B VAISSERMANN J
Citation
H. Rudler et al., ON THE FORMATION OF (CH3)(4)RE2O4 FROM METHYL TRIOXORHENIUM COMPLEX CH3REO3 UNDER NON-ALKYLATING CONDITIONS, Journal of organometallic chemistry, 548(2), 1997, pp. 295-299
Citations number
15
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
548
Issue
2
Year of publication
1997
Pages
295 - 299
Database
ISI
SICI code
0022-328X(1997)548:2<295:OTFO(F>2.0.ZU;2-1
Abstract
Attempts to deprotonate and alkylate at oxygen methyltrioxorhenium com plex (MTO) by means of nitrogen ylides PhC(O)CH-N+R1R2R3 led unexpecte dly to the known dinuclear Re(VI) complex Me4Re2O4 in 30% (R-1 = R-2 = R-3 = Et) and 72% (R-1 = Me, R2R3 = (CH2)(5)) yield, and to the corre sponding ammonium perrhenates ReO4-PhC(O)CH2N+R1R2R3. Both complexes c ould be fully characterized by their spectroscopic data and by X-ray c rystallography. (C) 1997 Elsevier Science S.A.