ELECTROCATALYTIC PROCESS IN THE REDUCTION OF (NB[ETA(5)-C5H4(SIME3)](2)(CL)(NHPH))BF4

Authors
TEHRANI ZM LUCAS D MUGNIER Y ANTINOLO A OTERO A FAJARDO M GARCES A LOPEZMARDOMINGO C
Citation
Zm. Tehrani et al., ELECTROCATALYTIC PROCESS IN THE REDUCTION OF (NB[ETA(5)-C5H4(SIME3)](2)(CL)(NHPH))BF4, Journal of organometallic chemistry, 548(2), 1997, pp. 309-313
Citations number
51
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
548
Issue
2
Year of publication
1997
Pages
309 - 313
Database
ISI
SICI code
0022-328X(1997)548:2<309:EPITRO>2.0.ZU;2-9
Abstract
Protonation of the biscyclopentadienyl imido niobium complex (eta(5)-C 5H4SiMe3)(2)Nb(Cl)(=NPh) affords the corresponding cationic amido comp lex [(eta(5)-C5H4SiMe3)(2)Nb(Cl)(NHPh)](+), 1. Starting from 1, an int eresting amido group elimination reaction has been found to take place , reaction which must be electrochemically induced. (C) 1997 Elsevier Science S.A.