SYNTHESIS AND CHARACTERIZATION OF MOLYBDENUM-CONTAINING SILICALITE-2 (MOS-2) MOLECULAR-SIEVE

Authors
RAGHAVAN PS KANNAN S BELHEKAR AA
Citation
Ps. Raghavan et al., SYNTHESIS AND CHARACTERIZATION OF MOLYBDENUM-CONTAINING SILICALITE-2 (MOS-2) MOLECULAR-SIEVE, Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical, 36(10), 1997, pp. 905-907
Citations number
12
Journal title
Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical
ISSN journal
03764710 → ACNP
Volume
36
Issue
10
Year of publication
1997
Pages
905 - 907
Database
ISI
SICI code
0376-4710(1997)36:10<905:SACOMS>2.0.ZU;2-A
Abstract
Microporous molybdenum containing silicalite-2 (MoMEL) has been synthe sized hydrothermally, under aluminium free alkaline conditions. Physic ochemical characterization of the sample (XRD, FTIR, UV-Vis and TG/DTA ) has revealed the possible incorporation of molybdenum ions in the ze olite framework. MoMEL is active in the oxidative dehydrogenation of e thanol to acetaldehyde with about 40% conversion at 673 K with a selec tivity of 90%.