CATALYTIC TRANSFORMATION OF (-)-LIMONENE OXIDE OVER BINARY OXIDE CATALYSTS OF ALUMINA RARE-EARTHS

Authors
JAYASREE J
Citation
J. Jayasree, CATALYTIC TRANSFORMATION OF (-)-LIMONENE OXIDE OVER BINARY OXIDE CATALYSTS OF ALUMINA RARE-EARTHS, Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical, 36(9), 1997, pp. 765-768
Citations number
32
Journal title
Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical
ISSN journal
03764710 → ACNP
Volume
36
Issue
9
Year of publication
1997
Pages
765 - 768
Database
ISI
SICI code
0376-4710(1997)36:9<765:CTO(OO>2.0.ZU;2-E
Abstract
The transformation reaction of (-)-limonene oxide over single oxides l ike Al2O3, Y2O3, Nd2O3, Sm2O3, Eu2O3 and binary oxides like Al2O3-Y2O3 , Al2O3-Sm2O3, Al2O3-Eu2O3 Al3O3-Pr6O11 and Al2O3-Nd2O3 are discussed. The catalysts show selectivity for allyl alcohol formation. trans-exo -Carveol (2) and cis-endo-carveol (3) are the major products formed at 140 degrees C and 110 degrees C respectively.