Vm. Pergamenshchik et al., K-13-INDUCED DEFORMATIONS IN A NEMATIC LIQUID-CRYSTAL - EXPERIMENTAL TEST OF THE FIRST-ORDER THEORY, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 292, 1997, pp. 25-37
We consider predictions of the so-called ''first-order elastic theory'
' with non-zero elastic constant K-13 for a nematic cell with tilted m
olecular orientation. The geometry has been suggested by Faetti to tes
t the validity of different theoretical approaches to the problem of t
he divergence K-13 elastic term. According to the first order elastic
theory, in which only the first and second derivatives in the elastic
free energy are retained, the K-13 term causes deformations at the cel
l surface when a magnetic field is applied along the initial director
n. These deformations can be observed in the measurements of the optic
al phase retardation; the distinctive feature of the K-13 effect is no
n-monotonous behavior of the phase retardation when the magnetic field
increases. Despite a number of difficulties, the effect can be tested
experimentally. We report experimental data on the behavior of the ne
matic cell with a high pretilt angle and weak anchoring in a tilted ma
gnetic field. These results show no significant deviation in the monot
onous behavior of the phase retardation; therefore, the experiment doe
s not confirm the predictions of the first-order theory when K-13 not
equal 0.