K. Praefcke et al., AMPHOTROPIC PROPERTIES OF MULTI-PALLADIUM AND MULTI-PLATINUM LIQUID-CRYSTALS, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 292, 1997, pp. 123-139
Tetrametallomesogens containing palladium (2,3a-c) or platinum (4,5a-c
) macroheterocyclic central cores show wide ranging liquid crystalline
properties, both thermotropic and lyotropic in apolar organic solvent
s. Here, we present an overview of recent work from our laboratory con
cerning these novel metallomesogens and related bis-metal analogues 6
and 7. We also propose new nomenclature to satisfy the growing range o
f liquid crystalline mesophases exhibited by these materials.