Pe. Cladis, FLEXOELECTRIC INDUCED VANISHING OF THE CHOLESTERIC HELIX, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 292, 1997, pp. 147-154
In the cholesteric liquid crystal helix structure, the director, n, ro
tates in a plane about an axis, t(0) perpendicular to n, with a consta
nt twist, n.curln = -q. The inverse helix pitch is defined by q = 2 pi
/pitch. Here we show that in the limit of a small electric field, E, a
pplied perpendicular to t(0), a solution to the minimizer of the elast
ic free energy, including a linear coupling between E and splay/bend d
eformations of n (the flexoelectric term), is one where the director d
evelops a small periodic component parallel to t(0). As the wave numbe
r of this distortion is also q, the net effect is a rotation of the op
tic axis by a small angle relative to t(0). There is no threshold for
this effect when the dielectric anisotropy epsilon(a) is greater than
epsilon(a) > -8 pi e(2)/K. e is the flexoelectric coefficient and K is
an elastic constant. When E parallel to t(0) and epsilon(a) > 0, it i
s well-known that this director configuration can be created by bounda
ry conditions. In which case, above a critical field, E-c, the cholest
eric helix transforms to a uniform director field with n parallel to t
(0), without q --> 0 continuously and without introducing defects. As
this is similar to solutions presented here when E perpendicular to n
but epsilon(a) < 0, the suggestion is that flexoelectricity could medi
ate a similar commensurate defect free vanishing of the cholesteric he
lix in this case. When epsilon(a) > 0, the conclusion is that a defect
free transformation of the cholesteric helix to a uniform director fi
eld with n parallel to E requires the assistance of induced flows.