FLEXOELECTRIC INDUCED VANISHING OF THE CHOLESTERIC HELIX

Authors
Citation
Pe. Cladis, FLEXOELECTRIC INDUCED VANISHING OF THE CHOLESTERIC HELIX, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 292, 1997, pp. 147-154
Citations number
23
Categorie Soggetti
Crystallography
ISSN journal
1058725X
Volume
292
Year of publication
1997
Pages
147 - 154
Database
ISI
SICI code
1058-725X(1997)292:<147:FIVOTC>2.0.ZU;2-X
Abstract
In the cholesteric liquid crystal helix structure, the director, n, ro tates in a plane about an axis, t(0) perpendicular to n, with a consta nt twist, n.curln = -q. The inverse helix pitch is defined by q = 2 pi /pitch. Here we show that in the limit of a small electric field, E, a pplied perpendicular to t(0), a solution to the minimizer of the elast ic free energy, including a linear coupling between E and splay/bend d eformations of n (the flexoelectric term), is one where the director d evelops a small periodic component parallel to t(0). As the wave numbe r of this distortion is also q, the net effect is a rotation of the op tic axis by a small angle relative to t(0). There is no threshold for this effect when the dielectric anisotropy epsilon(a) is greater than epsilon(a) > -8 pi e(2)/K. e is the flexoelectric coefficient and K is an elastic constant. When E parallel to t(0) and epsilon(a) > 0, it i s well-known that this director configuration can be created by bounda ry conditions. In which case, above a critical field, E-c, the cholest eric helix transforms to a uniform director field with n parallel to t (0), without q --> 0 continuously and without introducing defects. As this is similar to solutions presented here when E perpendicular to n but epsilon(a) < 0, the suggestion is that flexoelectricity could medi ate a similar commensurate defect free vanishing of the cholesteric he lix in this case. When epsilon(a) > 0, the conclusion is that a defect free transformation of the cholesteric helix to a uniform director fi eld with n parallel to E requires the assistance of induced flows.